Last opdate:
2017: Tuesday, 18. of April, 8.10 - 10 and Thursday, 20. of April (in 28B.0-5) and
Thursday 20. of April, 13 - 17 in the South-lab in 15.2
Case study 5 continued
Group 2 metals.
Sections 12.4, 12.8.
Table 12.1
Note: Group 2 table of some properties (Home page and Moodle)
End of chapter problems 12.22, 12.24.
Group 12 metals: Sect. 22.13 (zinc) 23.13 (cadmium and mercury)
- Coordination types and characteristic coordination compounds
- Common aqueous chemistry and the identification of Zn, Cd and Hg
- Hg(I) is Hg22+; from where do we know?
- Zink ions in metallo-proteins, Sect 29.5
Iron: sect.21.9, "Iron in two oxidation states" and
Lecture notes: Iron
Group 10: Nickel, Palladium and Platinum
Sect. 21.11 and 22.11
Lecture notes: Ni, Pd, Pt
Case study 3, cyanide as the ligand
In the lab we continue and finalise the Ni- and Fe-assignments
Next topic:
The d-block metals:
Study material: Chapter 21 (not sect 21.1, 21.2, - don't
focus on solid state structures, but merely on metal ion salts and coordination compounds with simpler ligands, since we meet a lot of other chemisty in the Case-studies) and Chapter 22 (only sect 22.3 and 22.11 as an example of a group, the Nickel-group.
Notes M2plus; M3plus; d-block-fluoride; d-block-chloride; Spin pairing energy table
Some short introductions will be given to all of these
(first row d-block) metals and much time will be spent on case studies.