Cu2+-en assignment: follow up. Did numbers behave?
Case studies 2 Q8-10.
Kinetics and mechanism Chapter 26 pp. 976-986 to Eigen-Wilkins mechanism (leave out "Ligand nuclephilicity"),
- Equilibrium and Kinetic Stability
- Reaction profile
- Mechanism of reaction
- Substitution in sqaure planar complexes: the trans effect
- The trans effect series
Case studies 2 Q5
Note: "How fast - how stable", End of chapter problems 26.4, 26.5, 26.7.
Ions and sizes.
Section 6.10-6.11, Note on Common crystal structures
Table 11.1, sections 11.4, 11.5, 11.6, 11.8.
- NaCl solid state structure and other structures
- The alkali metals, properties and reactivity, complex formation and solution chemistry.
- End of chapter problem 11.23, 11.25, 11.27, 11.28.
- K-Na-pumping
Please recall the PC-lab (Those who hasn't finalised the report, please do so) and prepare for the
Next Case study 5: Bidentate ligands
Preliminary:
Next topic
Group 2 metals.
Sections 12.4, 12.8.
Table 12.1
Note on group 2 metals
End of chapter problem 12.22, 12.24.
Group 12 metals: Sect. 22.13 (Zinc) 23.13 (cadmium and mercury)
- Coordination types and characteristic coordination compounds
- Common aqueous chemistry and the identification of Zn, Cd and Hg
- Hg(I) is Hg22+; from where do we know?
- Zink ions in metallo-proteins, Sect 29.5
Case study 3.