Chloro compounds of p-block elements (kp/oC) ® reaction with H2O/HCl

BCl3 (12.5) ® B(OH)3 CCl4 (76.7) NCl3 (71)

® HNO2

ClO2 (11)
® HClO2 +
ClO3-

FCl (-100)

AlCl3 Al2Cl6 (sub 180)
® AlCl4-
Al(H2O)63+
SiCl4 (57.6) ® Si(OH)4 PCl5 (sub 160)
®
POCl
3

PCl3 (76) ® H3PO3
S2Cl2 (14)
® H2S
SCl2 (59)

® H2SxOy

Cl2
(-34)

GeCl4 (83)

AsCl3 (130)
® H3AsO3 AsCl5 (d)
®
H3AsO4

SeCl2

(130 d)

ClBr (5)

SnCl4(114) ®
SnClx(OH)6-x 2-

SnCl2 ®
SnCl3 -

SbCl3(223)
® SbCl4-

SbCl5 (140 d) ® SbCl6-

Te4Cl4 (s)

I2Cl6 (s)

PbCl2 (s)

PbCl3-


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