Week 18

Last update:

2017: Tuesday, 2. of May 8.10-10 and Thursday 4. of May at 10.15 in 28B.0-05 and at 13 in the 15.2 - South lab .

Case study 7 , penicillamin as the ligand

Group 17 - The halogens Chapter 17
A few questions:
Phosphorpentafluoride is soluble in hydrogenfluoride. How could that be formulated in acid-base language?.
What is the geometry of BrF4+? (Use VSEPR theory)
What is the geometry of ClF4-? (Use VSEPR theory) What is VSEPR theory ? Consult section 2.8 . Aslo on the internet you may find a textbook-like outline of VSEPR with pictures and questions here

End of chapter problem 17.25

Case study 8: halogens

Next topic:
Group 16: O, S, Se, Te, Po Sect. 16.3-16.5, tables 16.7 and 16.8, End of chapter problem 16.26. Sect. 29.3, Iron-sulfur proteins in sect. 29.4
Allotropes of Oxygen.
Reactions with anthraquinol and similar diphenols
Oxygen contaning ligands
Biological oxygen transport
Sulfur, oxyacids, sulfur contaning ligands
Ordinary aqueous sulfur chemistry
Types of iron-sulfur proteins.

Case study 9 S, sulphur analogues


Thursday afternoon in the lab : Ion exchange separation of chromium(III) complexes (manual on Moodle and homepage)
Also look again at the Chromium case